Syntheses, Characterization And Biological Activity Of A New Ligend 3-[ (2z)-2-(Butane -2-Ylidene) Hydrazinyl] -5-Phenyl-4h-1,2,4-Triazole-4-Amine With Some Transition Metals Complexes

  • Farah J. Alhnon

Abstract

A new ligand 3-[(2Z)-2-(butane -2-ylidene)hydrazinyl] -5-phenyl-4H-1,2,4-triazole-4-amine with its (CrCl3.6H2O, FeCl3.6H2O, CoCl3, NiCl2.6H2O and CuCl2.6H2O) complexes were synthesized. The authenticity of the ligand and its transition metal complexes were established by elemental analyses, conductance, as well as spectroscopic (IR, 1H NMR, mass It may be concluded that the ligand coordinate through Nitrogen (N1) and Nitrogen (N1) atoms. This view is further supported by the appearance of a band corresponding to the metal–nitrogen stretching at 410–555 cm–1 in the complexes. The Ni and Cu atoms leading to the formation tetrahedral geometry. Octahedral geometry was proposed for the Cr(III), Fe(III) and Co(III) prepared complexes. All complexes and their parent organic moiety have been screened for antibacterial activity by using spread method and measurement inhibition zone by using dimethyl sulfoxide (DMSO). This studying showed positivity results. Since, it has shown lager inhibition zone against Escherichia coli and Staphylococcus Aurens.

Published
2020-04-06
How to Cite
Farah J. Alhnon. (2020). Syntheses, Characterization And Biological Activity Of A New Ligend 3-[ (2z)-2-(Butane -2-Ylidene) Hydrazinyl] -5-Phenyl-4h-1,2,4-Triazole-4-Amine With Some Transition Metals Complexes. International Journal of Advanced Science and Technology, 29(3), 7544 - 7551. Retrieved from http://sersc.org/journals/index.php/IJAST/article/view/7991
Section
Articles